The Governess, 60, confessed she liked the look of young entrepreneur Rob as he bowed out of the quiz after going for a high offer of £37,000.
The quizmaster admitted to Bradley Walsh: "He was very good – and cute."
Asking her to repeat it, the host simply couldn't believe her cheeky comment.
But Anne didn't back down, as she replied: "I said he was cute…"
As the audience laughed, Bradley told her: "Get a grip, woman!"
The Chaser responded quickly: "I can’t, he’s gone!"
It was all going well for Rob, until he was asked a question about who is the namesake of a Unicef Humanitarian Award.
Recently, 60-year-old quiz queen Anne revealed how her schedule has filled up since her stint in the I’m A Celeb jungle.
She told the Daily Star Sunday: "My schedule has gone bonkers and I find it overwhelming most of the time.
"Not a day goes by that I don't think it would be cool to retire."
After leaving the I'm A Celeb camp, Anne opened up about her struggles in the jungle and told hosts Holly Willoughby and Declan Donnelly that producers had to talk her out of quitting.
Anne said: "It was awful at the beginning, it was funny doing the swim across the lake and then we were walking and walking and I thought we were walking into hell.
"I couldn't process it, it was like the reality hit me and I was like what have I done, what was I thinking?
"I went into the Bush Telegraph the next day and said I quit and they said give it a few hours."
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