The actress has played Charity for almost 20 years, and during that time she has had a dramatic on-off relationship with her cousin Cain.
The pair have daughter Debbie together, and while Charity has just proposed to Vanessa, Emma thinks the bad boy could still be "The One".
Emma, 43, appeared on today's Lorraine, and when the host said Charity appeared to have found her soul mate, she replied: "Although, I always say Cain and Charity.
"Never say never in soaps because they always change but at the moment it’s going great."
The news will be a blow to fans of 'Vanity', Charity and Vanessa's couple name, but Emma reassured them that her alter ego was perfectly happy in her relationship at the moment.
She added: "Charity has fallen in love with a woman. It’s good, it works.
"I don’t know if she’d ever go back to being with a man now.
"I guess she probably could because she can do anything – It’s working for now and Michelle and I have a good comradery. It’s just so different."
Last night, viewers were left shocked as Cain – played by Jeff Hordley – kissed Charity.
The Dales bad boy let his emotions get the better of him as Charity tried to persuade him he could win girlfriend Moira Barton back after lashing out at her in a violent attack.
The pair got close as Charity placed her hand on Cain's arm, their faces just inches apart.
After telling her he didn't think he could resolve the situation, he kissed her on the lips, leaving her stunned.
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