Jurgen Klopp's side must beat Carlo Ancelotti's men at Anfield to stand any chance of reaching the knockout stages.
How can I watch Liverpool vs Napoli for FREE?
The Champions League clash will be shown live on BT sport 2 or BT Sport 4K UHD.
BT subscribers can stream the match on their mobile, tablet or laptop by downloading the BT Sport app.
However, EE customers can also catch all the action live for FREE by texting SPORT to 150 or call 07953 966502 to sign up for a free three-month BT Sport subscription.
You will then be sent instructions where you will be able to watch via the BT Sport app.
EE will allow you free casting to your TV during the three-month period as well.
However, once your free trial is up, you may be charged the normal fee of £5 a month to watch via the app and £10 a month for casting.
You can cancel at any time during your three-month subscription.
Alternatively, you can keep up to date with all of the action on the SunSport live blog.
When is Liverpool vs Napoli?
This match will take place TONIGHT.
Liverpool's Anfield stadium will host the showdown.
Kick-off will be at 8pm.
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